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Photoacoustic Investigation of Carrier Transport and Thermal Diffusivity in GaAs and Si
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ÀÓÁ¾Å ( Lim Jong-Tae ) - Yonsei University Department of Chemistry
ÇÑÈ£¿¬ ( Han Ho-Youn ) - Yonsei University Department of Chemistry
¹Ú½ÂÇÑ ( Park Seung-Han ) - Yonsei University Department of Physics
±è¿õ ( Kim Ung ) - Yonsei University Department of Physics
ÃÖÁß±æ ( Choi Joong-Gill ) - Yonsei University Department of Chemistry
KMID : 1059519970410070329
Abstract
±¤À½Ç⠺б¤¹ýÀ» ÀÌ¿ëÇÏ¿© GaAs¿Í S1 ¹ÝµµÃ¼¿¡¼ ¿î¹ÝÀÚ ¿î¼ÛƯ¼ºÀ» ¿¬±¸ÇÏ°í ¿È®»êµµ¸¦ ÃøÁ¤ÇÏ¿´´Ù. º¯Á¶Á֯ļö¿¡ µû¸¥ ¹ÝµµÃ¼ÀÇ ±¤À½Çâ½ÅÈ£¿Í À§»óÀ¸·ÎºÎÅÍ ¹ÝµµÃ¼¿¡¼ÀÇ ¿î¹ÝÀÚ Æ¯¼ºÀÌ ³·Àº Á֯ļö¿µ¿ª¿¡¼´Â ÁÖ·Î ¼ø°£ÀûÀÎ ¿¿ø¿¡ ÀÇÇϸç, ³ôÀº Á֯ļö¿µ¿ª¿¡¼´Â ºñ¹æ»ç ¹úÅ©Àç°áÇÕ°ú ºñ¹æ»ç Ç¥¸éÀç°áÇÕ¿¡ÀÇÇÑ È¿°úÀÓÀ» °üÂûÇÏ¿´´Ù. GaAs¿Í °°Àº Á÷Á¢ÀüÀÌ ¹êµå°¸À» °®´Â ¹ÝµµÃ¼ÀÇ °æ¿ì À§ÀÇ ¼¼°¡Áö ±¤À½ÇâÈ¿°ú¸¦ ¸ðµÎ ³ªÅ¸³»´Â ¹Ý¸é, Si°ú °°Àº °£Á¢ÀüÀÌ ¹êµå°¸À» °®´Â ¹ÝµµÃ¼ÀÇ °æ¿ì ¼ø°£ÀûÀÎ ¿¿ø¿¡ ÀÇÇÑ È¿°ú¿Í ºñ¹æ»ç ¹úÅ©Àç°áÇÕ¿¡ ÀÇÇÑ È¿°ú¸¸À» º¼ ¼ö ÀÖ¾ú´Ù. ÀÌ·¯ÇÑ È¿°ú·Î º¯Á¶Á֯ļö¿¡ µû¸¥ ±¤À½Çâ½ÅÈ£ÀÇ À§»ó¿¡¼ GaAs¹ÝµµÃ¼´Â ±Ø¼Ò°ªÀ» º¸ÀÌ´Â ¹Ý¸é Si ¹ÝµµÃ¼¿¡¼´Â ´ÜÁ¶°¨¼ÒÇÏ´Â °ÍÀ» °üÂûÇÒ ¼ö ÀÖ´Ù. ¾Æ¿ï·¯ ±¤À½Çâ½ÅÈ£·ÎºÎÅÍ ¹ÝµµÃ¼ ½Ã·áÀÇ ¿È®»êµµ ¡ð3¸¦ °è»êÇÏ¿´À¸¸ç ÃøÁ¤µÈ ¿È®»êµµ ¡ð´Â GaAsÀÇ °æ¿ì 0.35 cm2/s À̰í SiÀÇ °æ¿ì1.24cm2/s¸¦ ¾ò¾ú´Ù. ¶ÇÇÑ ±¤À½Çâ½ÅÈ£ÀÇ À§»óÀ» curve fittingÇÏ¿© ¿È®»êµµ¸¦ ÃøÁ¤ÇÑ °á°ú ±¤À½Çâ½ÅÈ£·Î ºÎÅÍ ±¸ÇÑ °ª°ú À¯»çÇÑ ¿È®»êµµ¸¦ ±¸ÇÒ ¼ö ÀÖ¾ú´Ù.
Photoacoustic spectroscopy was utilized to investigate the carrier tmnsport and the thermal diffusivity in GaAs and Si. From the frequency dependence of the photoacoustic signal, it is found that heat source was originated from the instantaneous thermahzation process in low frequency region. In high frequency region, however, the heat was generated by the nonradiative bulk recombination and the nonradiative surface recombination processes. It was also shown that the photoacoustic effects in GaAs of a direct band gap were governed by all three processes and those in Si of an indirect band gap were produced by the instantaneous thermalization and the nonradiative bulk recombination only. The phase of the photoacoustic signal showed a minimum value in GaAs. In Si, the phase of the photoacoustic signal was monotonically decreased as the modulation frequency was increased, demonstrating the above-mentioned mechanisms of the generation of heat. By measuring the photoacoustic signal, thermal diffusivities of semiconductors were determined to be ~0.35 cm2/s for GaAs and ~1.24cm2/s for Si. In addition, the similar values of thermal diffusivities were obtained from the curve fitting of photoacoustic phase spectra.
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