Frequency Characteristics of Anodic Oxide Films
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À̵¿³ç, Yoon Young-Ku,
¼Ò¼Ó »ó¼¼Á¤º¸
À̵¿³ç ( Lee Dong-Nyung )
Korea Institute of Science and Technology
( Yoon Young-Ku )
Korea Atomic Energy Research institute
KMID : 0371819740060010014
Abstract
¾Æ³ë´ÙÀÌ¡ Àü¾ÐÀÌ ÅºÅ»¾ç±Ø»êÈÇǸ·ÀÇ Á֯ļö Ư¼º¿¡ ¹ÌÄ¡´Â ¿µÇâÀ» ´ÙÀ½ ÀÓÇǴܽº ½ÄÀ» ÀÌ¿ëÇÏ¿© ºÐ¼®ÇÏ¿´´Ù.
1/C_(1)=(1n¥ø¥ó_(¥ø)+Pln(¥ó_(¥ø)/¥ó_(o))/(C_(o)(1+P)ln(¥ó_(¥ø)/¥ó_(o))
tan ¥ä_(f)=_(¥ø)C_(f)R_(f)=(¥ø¥ó_(¥ø)(¥ð/2-tan^(-1)¥ø¥ó_(o))+Pln(¥ó_(¥ø)/¥ó_(o)))/(¥ø¥ó_(¥ø)(ln(¥ø¥ó_(¥ø)+Pln(¥ó_(¥ø)/¥ó_(o)))
¿©±â¼ R_(f), C_(f), tan ¥ä_(f)´Â °¢°¢ ¾ç±Ø»êÈÇǸ·ÀÇ µî°¡Á÷·ÄÀúÇ×, µî°¡Á÷·Ä¿ë·®, À¯Àü¼Õ½ÇÀÌ´Ù. ÆÄ¶óµ¥Å¸ P, ¥ó_(o), ¥ó_(¥ø), C_(o)´Â ´ÙÀ½°ú °°ÀÌ Á¤ÀǵȴÙ.
P=(d-¥ø)/¥ø
¥ó_(o)=¥ê¥ñ_(o)
¥ó_(¥ø)=¥ê¥ñ_(¥ø)
C_(o)=¥êA/d
¿©±â¼ d ´Â ¾ç±Ø»êÈÇǸ·ÀÇ µÎ²², ¥ø´Â È®»êÃþÀÇ µÎ²², ¥ñ_(o)´Â ±Ý¼Ó°ú»êȹ°ÀÇ °è¸é¿¡¼ÀÇ »êȹ°ÀÇ ºñÀúÇ×, ¥ñ_(¥ø)´Â ¾ç±Ø»êÈÇǸ·ÀÇ Áø¼º¿µ¿ª¿¡¼ÀÇ ºñÀúÇ×, A´Â ¾ç±Ø»êÈ ÇǸ·ÀÇ ¸éÀûÀ̸ç, ¥ê=0.0885¡¿10^(-12)¡¿À¯Àü»ó¼ö(in farad/§¯).
µî°¡Á÷·Ä¿ë·®ÀÇ Á֯ļö¿¡ µû¸¥ º¯È¿Í À¯Àü¼Õ½ÇÀº ¾Æ³ë´ÙÀÌ¡Àü¾ÐÀÌ Áõ°¡ÇÔ¿¡ µû¶ó °¨¼ÒÇÏ¿´´Ù. ÀÌ Çö»óÀº »êÈÇǸ·ÀÇ È®»êÃþÀÇ µÎ²²°¡ ¾Æ³ë´ÙÀÌ¡Àü¾ÐÀÌ Áõ°¡ÇÔ¿¡ µû¶ó ¾à°£ Áõ°¡ÇÏ´Â ¹Ý¸é ¼±ÈÇǸ· ÀüüµÎ²²´Â ¾Æ³ë´ÙÀÌ¡Àü¾Ð¿¡ ºñ·ÊÇÏ¿© Áõ°¡ÇÑ´Ù´Â »ç½Ç¶§¹®ÀÌ´Ù.
½ÇÇèÃøÁ¤Ä¡°¡ tan ¥ä_(f)=0.682¥ÄC_(f)°ü°è½ÄÀ¸·ÎºÎÅÍ Ý¶·Î ÀÌÅ»Çϴ°ÍÀ» À§ÀÇ ÀÓÇǴܽº½Ä¿¡ ¹ÙÅÁÀ» µÎ°í °ËÅäÇÏ¿´´Ù. ¿©±â¼ ¥ÄC_(f)´Â 0.1°ú 1KHZ »çÀÌ¿¡¼ÀÇ ¿ë·®º¯ÈÀÌ´Ù.
Effects of anodization voltage on frequency characteristics of anodic oxide films on tantalum were analyzed based on the following impedance equations:
1/C_(1)=(1n¥ø¥ó_(¥ø)+Pln(¥ó_(¥ø)/¥ó_(o))/(C_(o)(1+P)ln(¥ó_(¥ø)/¥ó_(o))
tan ¥ä_(f)=_(¥ø)C_(f)R_(f)=(¥ø¥ó_(¥ø)(¥ð/2-tan^(-1)¥ø¥ó_(o))+Pln(¥ó_(¥ø)/¥ó_(o)))/(¥ø¥ó_(¥ø)(ln(¥ø¥ó_(¥ø)+Pln(¥ó_(¥ø)/¥ó_(o)))
Here Rf, Cf and tan of are equivalent series resistance in ohm, equivalent series capacitance in farad and dielectric loss of anodic oxide films respectively Parameters P, rc, Tw and Co are defined as follows:
P=(d -w)/w
To=kTo
Tw=xPw
Co=kA/d
where d is the thickness of oxide film, w is the diffusion layer thickness, po is the resistivity of oxide film at the interface of metal and the oxide, pw is the resistivity of oxide film at intrinsic region and A is the area of the film and c=0. 5X10-12Xdielectric constant, (in farad/cm).
It was shown that dielectric loss and frequency dependence of equivalent series capacitance decrease as anodization voltage increases. This is a consequence of the fact that the thickness of diffusion layer increases a little with increasing anodization voltage whereas the total oxide thickness is proportional to the anodization voltage.
The ngative deviation of measured values from the relation, tan of=0.682 dCf, was also discussed based on the impedance equations given above. Here dCf is the change in capacitance between 0.1 and 1 KHZ
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