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Electrochemical Sensing of Hydrogen Peroxide Using Prussian Blue@poly(p-phenylenediamine) Coated Multi-walled Carbon Nanotubes

Journal of the Korean Chemical Society 2023년 67권 5호 p.339 ~ 347
Rashmi A. Rupasinghe, 장원형, 이경곤, 홍훈기,
소속 상세정보
 ( Rashmi A. Rupasinghe ) 

장원형 ( Jang Won-Hyeong ) 

이경곤 ( Lee Gyeong-Geon ) 

홍훈기 ( Hong Hun-Gi ) 

Abstract


In this study, a nanocomposite of multi-walled carbon nanotubes@poly(p-phenylenediamine)-Prussian blue (MWCNTs@PpPD-PB) was synthesized and employed for the electrochemical detection of hydrogen peroxide (H2O2). A straightforward approach was utilized to prepare an electrochemical H2O2 sensor using a MWCNTs@PpPD-PB modified glassy carbon electrode, and its electrochemical behavior was investigated through techniques such as electrochemical impedance spectroscopy, cyclic voltammetry, and amperometry. The modified electrode displayed a favorable electrocatalytic response towards the reduction of H2O2 in an acidic solution. The developed sensor exhibited linearity in the concentration range of 0.005 mM to 2.225 mM for H2O2, with high sensitivity (583.6 μA mM-1cm-2) and a low detection limit (0.95 μM, S/N = 3) at an applied potential of +0.15 V (vs. Ag/AgCl). Additionally, the sensor demonstrated excellent selectivity, reproducibility, and stability. Moreover, successful detection of H2O2 was achieved in real samples.

키워드

Prussian blue; Poly(p-phenylenediamine); Multi-walled carbon nanotubes; Hydrogen peroxide; Amperometry; Sensor

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